COMPUTATIONAL AND SPECTROSCOPIC CHARACTERIZATIONS OF SOME N-ALKYL (BENZYL)-DIAZENIUM DIOLATES AND ..

The computational (DFT/ B3LYP) and spectroscopic (UV-VIS) structures and spectroscopic properties of a series of N-alkyl(benzyl)-N-nitroso hydroxylamines at deprotonation (diazenium diolates) and complex formation were examined. The molecular and electrical structures, as well as the bond character, of complexes with various metal ions are detailed. The DFT calculations' results do not contradict the crystal structure determination data or the spectrum properties of the complexes.

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