CROSSLINKED ORGANIC–INORGANIC POLY(IONIC LIQUID) HYBRID FILMS PREPARED BY COMBINING SOL-GEL AND ....
The sol-gel process was used to create polymerizable organic-inorganic TiO2 hybrid sols (TiO2 hybrid sol). To make an inorganic-organic poly(ionic liquid) (PIL) hybrid, this TiO2 hybrid sol was blended with vinylimidazolium-based ionic liquids and subsequently free-radical copolymerized. The TiO2 hybrid sol was successfully incorporated into the networks of PIL polymers, according to the results. The conductivity of the PIL hybrids increases as the TiO2 hybrid sol content increases, reaching a maximum of 1.0410-4.5 Scm-1. The thermal stability of the resultant hybrids improves when inorganic components are added. The integral procedure decomposition temperature (IPDT) of Doyle's approach was used in thermogravimetric analysis (TGA) to correlate the volatile components of polymeric materials and to estimate the intrinsic thermal stability of polymeric materials. Pure PILs had an IPDT of 416°C, while hybrids had IPDTs that were greater than pure PILs. When inorganic components were added to PIL at a concentration of 3.89 wt percent, the electrical conductivity was 10-4.5 Scm-1, compared to 10-4.8 Scm-1 for pure PILs.
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